| 1 | 1 | Vicky Macintosh, Danel Louw | 30-34 | 55:02 | Analyze |
| 2 | 2 | Andrea Erasmus, Carien Fourie | 30-34 | 1:03:25 | Analyze |
| 3 | 1 | Stephani van Zyl, Margot Rademeyer | 25-29 | 1:06:13 | Analyze |
| 4 | 2 | Octavia De Sa, Tatiana Martins | 25-29 | 1:06:54 | Analyze |
| 5 | 1 | Melissa Clarke, Shani de Witt | 35-39 | 1:07:00 | Analyze |
| 6 | 3 | Heléne Coetzer, Lara Bruwer | 30-34 | 1:07:10 | Analyze |
| 7 | 4 | Uleen Fourie, Bernette Bester | 30-34 | 1:07:47 | Analyze |
| 8 | 3 | Olivia Gearing, Sasha Domnick | 25-29 | 1:08:11 | Analyze |
| 9 | 1 | Isabella Winter, Ashton Weir | 16-24 | 1:08:55 | Analyze |
| 10 | 2 | Riana Van Heerden, Michaela Meintjes | 35-39 | 1:10:34 | Analyze |
| 11 | 3 | Bronwyn Shand, Abigail Keats | 35-39 | 1:10:56 | Analyze |
| 12 | 4 | Ashleigh Botha, Morgen-Emma Reed | 35-39 | 1:12:33 | Analyze |
| 13 | 5 | Marchanne De Bruyn, Nikki Carter | 30-34 | 1:12:37 | Analyze |
| 14 | 1 | Claudia Hazelwood, Laura Smal | 40-44 | 1:13:38 | Analyze |
| 15 | 4 | Lucinda Bosch, Danielle Jordaan | 25-29 | 1:13:52 | Analyze |
| 16 | 2 | Lané Du Plessis, Susan Buys | 40-44 | 1:14:27 | Analyze |
| 17 | 5 | Chrisna Campher, Jenna Yeats | 35-39 | 1:14:35 | Analyze |
| 18 | 3 | Natalie Agostinho, Amy Cohen | 40-44 | 1:15:21 | Analyze |
| 19 | 6 | Rezelle Secchia, Miranda Beringer | 35-39 | 1:16:00 | Analyze |
| 20 | 2 | Tatijana Ignjatov, Vesna Ignjatov | 16-24 | 1:17:04 | Analyze |
| 21 | 7 | Phelisa Mtsewu, Pressya Ndongala | 35-39 | 1:17:26 | Analyze |
| 22 | 4 | Elshe Naude, Mel De Morny | 40-44 | 1:18:18 | Analyze |
| 23 | 1 | Zsuzsanna Gyorgy, Mar-Loes Mantoua | 45-49 | 1:19:23 | Analyze |
| 24 | 2 | Claudia Monteiro, Lee-Ann Johns | 45-49 | 1:20:51 | Analyze |
| 25 | 8 | Neliswe Biyela, Kausar Shaik | 35-39 | 1:22:01 | Analyze |
| 26 | 9 | Rebecca Jopson, Natasha Shaw | 35-39 | 1:22:49 | Analyze |
| 27 | 5 | Lisa Mari Le Roux, Lize-Marie Vermeulen | 25-29 | 1:23:26 | Analyze |
| 28 | 5 | Ludivine Huet-Haupt, Tracey-Lee Johnson | 40-44 | 1:23:27 | Analyze |
| 29 | 6 | Beverley Siwisa, Georgia Love | 40-44 | 1:24:07 | Analyze |
| 30 | 6 | Tyler Spence, Samantha Wittmann | 25-29 | 1:29:31 | Analyze |
| 31 | 1 | Monica Dowie, Marisa Marais | 50-54 | 1:33:29 | Analyze |
| 32 | 3 | Anna Calivitis-Barnard, Matina Barnard | 16-24 | 1:42:08 | Analyze |
| 33 | 10 | Melissa Reyneke, Gabrielle D'arch | 35-39 | 1:42:18 | Analyze |
| 34 | 11 | Zimkhitha Nazo, Zanele Booi | 35-39 | 1:46:12 | Analyze |
| 35 | 12 | Nontobeko Nyalunga, Sibabalwe Mgijima | 35-39 | 1:47:11 | Analyze |
| 36 | 7 | Nosipho Sijula, Siyasanga Grace Tabata | 25-29 | 1:48:29 | Analyze |
| 37 | 3 | Babalwa Fede, Suratsawadi Mart | 45-49 | 2:08:45 | Analyze |
| 38 | 7 | Nonhlanhla Dlamini, Nomonde Kralo | 40-44 | 2:12:07 | Analyze |
| 39 | 6 | Yamkela Mroqo, Lelethu Magula | 30-34 | 2:17:16 | Analyze |
| 40 | 13 | Cordelia Masemola, Pearl Kgosimmele | 35-39 | 2:34:35 | Analyze |
| 41 | 8 | Nicolene Erasmus, Karen van Wyk | 40-44 | 2:36:20 | Analyze |